Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Stress corrosion cracking in a brewery paul mueller company. Austenitic stainless steels chloride induced stress corrosion cracking cscc chumpes petroleum 16 mar 18 10. The incubation time for stress corrosion cracking can be very short, sometimes measured in hours. The piping is currently constructed of 316l tubing. Stainless steel provides both strength and corrosion resistance inside the concrete, providing a long, maintenancefree service life of the structure. Hydrogen induced stress cracking of swaged super duplex stainless steel subsea components, corrosion. Pdf chloride induced stress corrosion cracking of type 304. Stresscorrosion cracking has been observed in absolute methanol. The effect of machininginduced surface residual stress on the stress corrosion cracking scc initiation in 316 stainless steel was investigated in boiling magnesium chloride solution. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Chloride induced stress corrosion cracking ciscc of stainless steel reactor components has occurred when three elements are all present. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. The important general point is that those environments that cause stress corrosion are frequently highly specific to the particular.
The three parameters l ss, steady state elongation rate. Stress corrosion cracking is a form of localized corrosion that. Chloride induced stress corrosion cracking of stainless steel water still. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. For solutions with a methanol content of 50% or more, the. The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Stress corrosion cracking of austenitic stainless steel type. Three underlying factors must be present to cause scc. Chloride stress corrosion cracking in austenitic stainless. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. The most damaging forms of stress corrosion cracking in austenitic stainless steels are chloride and caustic stress corrosion cracking and cracking in high temperature, high pressure aqueous environments. Past researched about scc of 310s primarily focus on the corrosion mechanism and influence of temperature and corrosive media, but few studies concern the.
Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Stress corrosion cracking of an austenitic stainless steel. The scc can be intergranular stress corrosion cracking igscc, transgranular stress corrosion cracking tgscc or be exhibited in a mixed mode of cracking. It is a recognized problem in the gas and oil industries, pipelines, municipal sewage treatment systems, and a variety of industrial applications. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Stress corrosion cracking of sensitized type 304 steel in low temperature borated water has been observed.
Stress corrosion cracking has been observed in absolute methanol. A water still failed due to water leaks in the shell. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Jun 27, 2019 the brittle nature of the fracture surface, calcareous deposits on the ferrule and exposure to cathodic protection suggested hydrogen induced stress cracking hisc. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Sep 18, 2017 fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. The five categories of stainless steels and key features essential for stress corrosion cracking are introduced. Stress corrosion cracking scc this is a relatively rare form of corrosion which requires a very specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur.
Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Methanolinduced corrosion is a type of corrosion induced by methanol. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. The process stream in low in organic chlorides, but high in hydrogen sulphide. Jun 11, 2015 a finiteelement computational model of chlorideinduced transgranular stresscorrosion cracking of austenitic stainless steel. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. A recent subsea failure of two subsea connectors made of uns s32760, a 25 wt% cr super duplex stainless steel, led to an extensive root cause failure analysis. This chapter investigates the stress corrosion cracking scc of a commercial austenitic stainless steel type 316 as a function of sensitizing temperature 8000 k in 0. Assessing stress corrosion cracking risks on stainless. Hisc is a term to refer to hydrogen stress cracking hsc of duplex and super duplex stainless steels dss and sdss, respectivelywhen exposed to hydrogen generated by cathodic.
This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain. Stress corrosion cracking in stainless steel question. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. The incubation time for crevice corrosion and pitting in seawater is relatively short, often only a few days. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Stress corrosion cracking scc is the main corrosion failure mode for 310s stainless steel. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Stress corrosion cracking facts and how to reduce the. Hydrogeninduced stress cracking of swaged super duplex.
The stress corrosion cracking in expanded parts of stainless steel heat exchangers and its prevention were studied. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Corrosion product filminduced stress facilitates stress. In this study, a layer of adsorbed product film enriched in chromium and nickel was found to form on the metal surface in the solutions. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Jun 10, 2016 310s is an austenitic stainless steel for high temperature applications, having strong resistance of oxidation, hydrogen embrittlement and corrosion. We have experienced repeated failures on seal flush piping on the naphtha and distillate reflux pumps in our crude fractionation unit. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. Effects of temperature and pressure on stress corrosion. Detecting and imaging stress corrosion cracking in. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. Chloride induced stress corrosion cracking of stainless steel.
Stainless steels are more resistant to general corrosion compared with carbon steel. On the stress corrosion cracking and hydrogen embrittlement. Stress corrosion cracking of an austenitic stainless steel in. Elevated stress susceptible material corrosive environment surface contamination by atmospheric chlorides sufficient humidity epri has a multiyear project to. Austenitic stainless steels chloride induced stress. Austenitic type 304 uns s30400 stainless steel is susceptible to stress corrosion cracking scc in acidic chloride cl. Stress corrosion cracking susceptibility of stainless steels. Stress corrosion cracking of austenitic stainless steel. Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. Chloride stress corrosion cracking inspectioneering. Assessing stress corrosion cracking risks on stainless steel. Hydrogen induced stress cracking of swaged super duplex. How to reduce the risk of stress corrosion cracking scc.
Figures 2,3,4 and 5 show the scc behaviour of type 304 austenitic stainless steel in dilute h 2 so 4 and expressed in terms of percentage elongation to fracture and in terms of reduction in cross sectional area. Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Jul 10, 2019 methanol induced corrosion is a type of corrosion induced by methanol. Corrosion behavior of austenitic stainless steel in sulphuric. The probable role of low levels of chloride ions or sulfurcontaining ions is described including the relationship to polythionic acid cracking. Thus, the addition of caustic soda to boiler feed waters to reduce the corrosiveness of the latter towards mild steel can result in the form of stress corrosion frequently referred to as caustic cracking. The effect of machining induced surface residual stress on the stress corrosion cracking scc initiation in 316 stainless steel was investigated in boiling magnesium chloride solution. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Stress corrosion cracking of austenitic type 304 stainless. Corrosion of unprotected carbon steel occurs even inside reinforced. Model test blocks of the exchangers were constructed with tubes expanded by. Discussion caustic stress corrosion cracking of steels is one of the oldest known forms of scc, dating back to the days of the early steam locomotives, when it was responsible for countless explosions of riveted boilers trethewey et al.
Chloride induced stress corrosion cracking ciscc of welded heat affected zones haz is of special concern, as it is a welldocumented mode of attack for austenitic stainless steels including 304hl and 316l in marine environments, and many isfsi sites are located in coastal areas. Corrosion resistance of stainless steels corrosion in concrete corrosion problems are not limited to outside surfaces. The interaction of corrosion fatigue and stresscorrosion. The use of material susceptible to stress corrosion cracking scc a precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Stress corrosion cracking facts and how to reduce the risk. Stress corrosion cracking susceptibility of stainless. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material.
Pdf stress corrosion cracking of stainless steel components. Stress corrosion cracking scc is a common issue with many specialty alloys. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. Stress corrosion cracking international institute of. Stress corrosion cracking scc is one of the most prevalent root causes of stainless steel failures in the refining industry. Pdf chloride induced stress corrosion cracking of type. In this chapter, the conditions for the occurrence of scc are first introduced. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment.